| |
“For the last 40 years or so, hand and spray lay-up have
been the predominant manufacturing processes for the production
of GFRP boats. They are relatively easy to work, allow the use
of female molds and, until recently, the regulations regarding
emissions were fairly relaxed. In fact, until the advent of
stricter emissions regulations, there was very little motivation
for the vast majority of boat builders to change their working
process.
|
Resin infusion done at our shop |
|
Hand/Lay-Up
Limitations
The most commonly used matrix for GFRP boats
is undoubtedly polyester resin. Polyester resins are produced
through a process of polycondensation between poly-basic acids
and polyvalent alcohol.
If the acid is unsaturated, these polyesters can
co-polymerize with styrene, the unsaturated monomer obtained
out of de-hydrogenation of the ethyl benzene at atmospheric
pressure and at about 600°C. The product that is created
is a polymer with a three-dimensional structure that
is inhible and insoluble.
Evaporation of the styrene during hand or spray laminating process
is a harmful chemical-physical process that is almost completely
eliminated by the use of infusion molding techniques.
However, in addition to the environmental issues, there are
many negative aspects to the hand/lay-up process, particularly
in terms of quality as the finished laminate is heavily dependent
on the relative skill of the individual.
Moreover, even when the skill level is high, it is difficult
to achieve fiber fractions of more than 40 percent and to eliminate
the problems associated with air entrapment.
Regarding mechanical properties, it is clear that laminates
manufactured using the infusion process are considerably superior
to those produced by hand lay-up. Four point bending tests to
ASTM 790 Norm show that infusion laminates have 20 percent higher
flexural strength than an equivalent hand lay-up laminate.” |